Anzar Khan 교수
학력 : Freie Universitat Berlin, 박사
연구분야 : Organic Polymer Chemistry
연구실 : 창의관 810C호 (TEL) 3290-4859
E-mail :
- 2005년 Freie Universitat Berlin, 박사
- 2006 - 2009년 : University of California, Santa Barbara, 연구원
- 2009 - 2015년 : ETH-Zurich Senior Scientist and Lecturer
- I) developing efficient, simple, and general synthetic methodologies for the preparation of multifunctional polymers
- II) developing methods to control the formation, dimensions, and chemical mapping of the polymeric nanostructured materials
주요 논문


1.??I. Gadwal,?A. Khan: “Multiply Functionalized Dendrimers: Protective-Group-Free Synthesis through Sequential Thiol-Epoxy ‘Click’ Chemistry and Esterification Reaction” RSC Adv. 2015, 5, 43961.

2.??J. Rao,?A. Khan: “Enzymatic ‘Charging’ of Synthetic Polymers” Polym. Chem. 2015, 6, 686.

3.??S. Kim, M. Yoo, J. Baettig, E. Kang, J. Koo, Y. Choe, T. Choi,?A. Khan, J. G. Son, J. Bang: “Perpendicularly Oriented Block Copolymer Thin Films Induced by Neutral Star Copolymer Nanoparticles” ACS Macro Lett. 2015, 4, 133.

4.??I. Gadwal, M. C. Stuparu,?A. Khan: “Homopolymer Bifunctionalization through Sequential Thiol-Epoxy and Esterification Reactions: An Optimization, Quantification, and Structural Elucidation Study” Polym. Chem. 2015, 6, 1393.

5.??C. Hoffmann, M. C. Stuparu, A. Daugaard,?A. Khan: “Aza-Michael addition reaction: Post-polymerization modification and preparation of PEI/PEG-based polyester hydrogels from enzymatically synthesized reactive polymers” J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 745.


6.??J. Rao, C. Hottinger,?A. Khan: “Enzyme-Triggered Cascade Reactions and Assembly of Abiotic Block Copolymers into Micellar Nanostructures” J. Am. Chem. Soc. 2014, 136, 5872.

7.??C. Buerkli, S. H. Lee, E. Moroz, M. C. Stuparu, J.-C. Leroux,?A. Khan: “Amphipathic Homopolymers for siRNA Delivery: Probing Impact of Bifunctional Polymer Composition on Transfection” Biomacromolecules, 2014, 15, 1707.

8.??I. Gadwal, S. Binder, M. C. Stuparu,?A. Khan: “Dual-Reactive Hyperbranched Polymer Synthesis through Proton Transfer Polymerization of Thiol and Epoxide groups” Macromolecules, 2014, 47, 5070.

9.??J. Rao, H. Ma, J. Baettig, S. Woo, M. C. Stuparu, J. Bang,?A. Khan: “Self-Assembly of an Interacting Binary Blend of Diblock Copolymers in Thin Films: A Potential Route to Porous Materials with Reactive Nanochannel Chemistry” Soft Matter, 2014, 10, 5755.

10.??I. Gadwal, J. Rao, J. Baettig,?A. Khan: “Functionalized Molecular Bottlebrushes” Macromolecules, 2014, 47, 35.

11.??S. Binder, I. Gadwal, A. Bielmann,?A. Khan: “Thiol-Epoxy Polymerization via an AB Monomer: Synthetic Access to High Molecular Weight Poly(ß-hydroxythio-ether)s” J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 2040.


12.??J. Rao,?A. Khan: “Enzyme Sensitive Polymer Micelles Based on the Azobenzene Motif” J. Am. Chem. Soc. 2013, 135, 14056.

13.??N. Cengiz, J. Rao, A. Sanyal,?A. Khan: “Designing Functionalizable Hydrogels through Thiol-Epoxy Coupling Chemistry” Chem. Commun. 2013, 49, 11191.

14.??J. Rao,?A. Khan: “Using Reversibility of the Dynamic Covalent Bond to Create Porosity in Highly Ordered Polymer Thin Films under Mild Conditions and Nano-pore Functionalization in the Gas Phase” Polym. Chem. 2013, 4, 2691 (Inside Cover Page).

15.??I. Gadwal,?A. Khan: “Protecting-Group-Free Synthesis of Chain-End Multifunctional Polymers by Combining ATRP with Thiol-Epoxy ‘Click’ Chemistry” Polym. Chem. 2013, 4, 2440 (‘Paper-of-the-Week’ 8th March 2013).


16.??A. Saha, S. De, M. C. Stuparu,?A. Khan: “Facile and General Preparation of Multifunctional Main-Chain Cationic Polymers through Application of Robust, Efficient, and Orthogonal Click Chemistries” J. Am. Chem. Soc. 2012, 134, 17291.

17.??J. Rao, S. De,?A. Khan: “Synthesis and Self-Assembly of Dynamic Covalent Block Copolymers: Towards a General Route to Pore-Functionalized Membranes” Chem. Commun. 2012, 48, 3427 (Highlight article in Chimia, 2012, 66, 444).

18.??S. De,?A. Khan: “Efficient Synthesis of Multifunctional Polymers via Thiol-Epoxy ‘Click’ Chemistry” Chem. Commun. 2012, 48, 3130.

19.??J. Rao, E. Paunescu, M. Mirmohades, I. Gadwal, A. Khaydarov, C. J. Hawker, J. Bang,?A. Khan: “Supramolecular Mimics of Phase Separating Covalent Diblock Copolymers” Polym. Chem. 2012, 3, 2050 (Top Ten most-read Polymer Chemistry article, May 2012).

20.??A. Brandle,?A. Khan: “Thiol-Epoxy ‘Click’ Polymerization: Efficient Construction of Reactive and Functional Polymers” Polym. Chem. 2012, 3, 3224 (Top Ten most-read Polymer Chemistry article, September 2012).

21.??M. C. Stuparu,?A. Khan, C. J. Hawker: “Phase Separation of Supramolecular and Dynamic Block Copolymers” Polym. Chem. 2012, 3, 3033 (Top Ten most-read Polymer Chemistry article, July 2012).

22.??S. De, C. Stelzer,?A. Khan:“A General Synthetic Strategy to Prepare Poly(Ethylene Glycol)-Based Multifunctional Polymers” Polym. Chem. 2012, 3, 2342.

23.??I. Gadwal, S. De, M. C. Stuparu,?A. Khan: “Effect of Precursor Chemical Composition on the Formation and Stability of Supramolecular Star Polymers” Polym. Chem. 2012, 3, 2615.

24.??I. Gadwal, S. De, M. C. Stuparu, R. J. Amir, S. Jang,?A. Khan: “Supramolecular Star Polymers with Compositional Heterogeneity” J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 1844 (Journal Cover Page).

25.??I. Gadwal, S. De, M. C. Stuparu, S. Jang, R. J. Amir,?A. Khan: “Effect of Precursor Chain Length on the Formation and Stability of Poly(ethylene glycol)-based Supramolecular Star Polymers” J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 2415.

26.??S. Jang,?A. Khan, C. J. Hawker, E. J. Kramer: “Morphology Evolution of PS-b-P2VP Diblock Copolymers via Supramolecular Assembly of Hydroxylated Gold Nanoparticles” Macromolecules, 2012, 45, 1553.


27.??R. J. Amir, L. Albertazzi, J. Willis,?A. Khan, T. Kang, C. J. Hawker: “Multifunctional Trackable Dendritic Scaffolds and Delivery Agents” Angew. Chem. Int. Ed. 2011, 50, 3425.

28. ?S. Jang,?A. Khan, M. D. Dimitriou, B. J. Kim, N. A. Lynd, E. J. Kramer, C. J. Hawker: “Synthesis of Thermally Stable Au-core/Pt-shell Nanoparticles and their Segregation Behavior in Diblock Copolymer Mixtures” Soft Matter, 2011, 7, 6255.


29. ?M. I. Montanez, L. M. Campos, P. Antoni, Y. Hed, M. V. Walter, B. T. Krull,?A. Khan, A. Hult, C. J. Hawker, M. Malkoch: “Accelerated Growth Dendrimers via Thiol-ene and Esterification Reactions” Macromolecules, 2010, 43, 6004.

30.??H. Nulwala, D. J. Burke,?A. Khan, A. Serrano, C. J. Hawker: “N-Vinyl Triazoles: A New Functional Monomer Family through Click Chemistry” Macromolecules, 2010, 43, 5474.

31.??T. Kang, R. J. Amir,?A. Khan, K. Ohshimizu, J. N. Hunt, K. Sivanandan, M. I. Montanez, M. Malkoch, Mitsuru Ueda, C. J. Hawker: “Facile Access to Internally Functionalized Dendrimers through Efficient and Orthogonal Click Reactions” Chem. Commun. 2010, 46, 1556.


32.??H. Nulwala, K. Takizawa, A. Odukale,?A. Khan, R. J. Thibault, B. R. Taft, B. Lipshutz, C. J. Hawker: “Synthesis and Characterization of Isomeric Vinyl-1,2,3-triazole Materials by Azide?Alkyne Click Chemistry” Macromolecules, 2009, 42, 6068.

33.??A. Khan, A. E. Daugaard, A. Bayles, S. Koga, Y. Miki, K. Sato, J. Enda, S. Hvilsted, G. D. Stucky, C. J. Hawker: “Dendronized Monomers for Three-Dimensional Data Storage” Chem. Commun. 2009, 425 (selected as Hot Article; highlighted in Chemical Technology 2009, 03 (cover page); New Scientist 21-Jan-2009 and 22-Jan-2009; among ‘Top Ten’ Chem. Commun. Articles in Jan 2009).


34.??A. Khan, G. D. Stucky, C. J. Hawker: “High-Performance, Non-diffusive Crosslinked Polymers for Holographic Data Storage” Advanced Materials 2008, 20, 3937.

35.??A. Khan, M. Malkoch, M. F. Montague, C. J. Hawker: “Synthesis and Characterization of Hyperbranched Polymers with Increased Chemical Versatility for Imprint Lithographic Resists” J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 6238.

36.??N. C. Strandwitz,?A. Khan, S. W. Boettcher, A. Mikhailovsky, C. J. Hawker, T. Nguyen, G. D. Stucky: “One- and Two-Photon Induced Polymerization of Methylmethacrylate Using CdS Semiconductor Quantum Dots” J. Am. Chem. Soc. 2008, 130, 8280.

37.??A. Khan, L. Campos, A. Mikhailovsky, M. Toprak, N. C. Strandwitz, G. D. Stucky, C. J. Hawker: “Holographic Recording in Crosslinked Polymeric Matrices through Photoacid Generation” Chem. Mater. 2008, 20, 3669.


38. ?A. Khan, S. Hecht: “Towards Photocontrolling the Helix-Coil Transition in Foldamers: Synthesis and Photoresponsive Behavior of Azobenzene-Core Amphiphilic Oligo(meta phenyleneethynylene)s”, Chem., Eur. J. 2006, 12, 4764.

39. ?A. Khan, C. Kaiser, S. Hecht: “Prototype of a Photoswitchable Foldamer” Angew. Chem. Int. Ed. 2006, 45, 1878. (Highlighted in MRS Bulletin 2006, 31, 288; Nachrichten aus der Chemie 2006, 54, 208)

40. ?A. Khan, S. Hecht: “Poly(ortho-phenylene ethynylene)s: Synthetic Accessibility and Optical Properties” J. Polym. Sci., Part A: Polym. Chem. 2006, 44(5), 1619.


41.??A. Khan, S. Muller, S. Hecht: “Practical Synthesis of an Amphiphilic, Non-Ionic Poly(para-phenyleneethynylene) Derivative with a Remarkable Quantum Yield in Water” Chem. Commun. 2005, 584.

42. ?M. A. Balbo Block, C. Kaiser,?A. Khan, S. Hecht: “Discrete Organic Nanotubes Based on a Combination of Covalent and Non-Covalent Approaches” Top. Curr. Chem., 2005, 245, 89.


43.??A. Khan, S. Hecht: “Functional Organic Nanotubes from Hollow Helical Scaffolds” Synth. Met. 2004, 147, 37.

44.??A. Khan, S. Hecht: “Microwave-Assisted Synthesis of Lengthy and Defect-Free Poly(m-phenyleneethynylene)s via AB’ and A2+BB’ Polycondensation Routes” Chem. Commun. 2004, 300.

45.??M. A. Balbo Block,?A. Khan, S. Hecht: “Avenues into the Synthesis of Illusive Poly(m-phenylene-alt-squaraine)s: Polycondensation of m-Phenylenediamines with Squaric Acid Intercepted by Intermediate Semisquaraines of Exceptionally Low Reactivity” J. Org. Chem. 2004, 69, 184.

46.??S. Hecht,?A. Khan: “Intramolecular Crosslinking of Helical Folds: A Novel Approach to Organic Nanotubes” Angew. Chem. Int. Ed. 2003, 42, 6021. (Highlighted in Nature Materials, 2004, 8, 507)